Angew. Budukva, S.V., Klimov, O.V., Chesalov, Y.A., Prosvirin, I.P., Larina, T.V., and Noskov, A.S., Catal. Chem.
Molybdenum and nickel-molybdenum nitride catalysts supported on MgO Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption.
Understanding the Hydrogen Evolution Reaction Kinetics of This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis, project AAAA-A21-121011890074-4. Soc. Science 352, 7376 (2016). A structural model for metallic glasses. St. John, S., Atkinson, R. W., Unocic, R. R., Zawodzinski, T. A.
Hydrogen oxidation on PdIr/C catalysts in alkaline media. Cong, Y. et al. Here we show that a nickel-molybdenum nanoalloy with tetragonal MoNi 4 phase can catalyze the HOR efficiently in alkaline electrolytes. Versatile nickeltungsten bimetallics/carbon nanofiber catalysts for direct conversion of cellulose to ethylene glycol. For relatively lower Ni doping amounts, i.e., Ni/Mo molar ratio = 0.8/99.2 to 2.4/97.6, the catalysts exhibited almost the same methanol conversion in the reaction temperature range. PubMed Ohyama, J., Sato, T., Yamamoto, Y., Arai, S. & Satsuma, A. Yang, X., Nash, J., Oliveira, N., Yan, Y. Phys. Bard, A. J. Chem. . Soc. Recent research on AEM water electrolyzers has shown that NiMo catalysts are the most active catalysts for the HER under highly alkaline conditions, leveraging Ni atoms as excellent water dissociation centers, coupled with Mo atoms providing superior adsorption properties towards hydrogen [ [16], [17], [18], [19], [20] ]. Soc. Modifying the closely stacked MEC design to include a reference electrode, and analysis of the electrode potentials using the electrode potential slope method, revealed a large contribution of the cathode resistance (5.3 0.5 m m2) compared to the anode (1.4 0.2 m m2) and ohmic resistance (0.83 m m2) for a total internal resistance of 7.6 0.5 m m2. 595655. Bulk Metallic glass nanowire architecture for electrochemical applications. Phys. By introducing transition metal Ni into the Mo 2 N lattice to form nickel-molybdenum bimetallic nitride, . Catal., A, 2004, vol. Nanostructured nickel nanoparticles supported on vulcan carbon as a highly active catalyst for the hydrogen oxidation reaction in alkaline media. Eur. "Our biggest challenge was to explain why our catalyst worked so well," says Yavuz. Daud, W. R. W. et al. A. Sci. A minimum of four hours is necessary to complete the presulfiding step. ISSN 2520-1158 (online). carried out the XRD measurements. Perdew, J. P., Burke, K. & Ernzerhof, M. Generalized gradient approximation made simple. The hydrogen evolution/oxidation reaction. Scr. Int. Russ. 52, 36973700 (2016). C, 2010, vol. Nickel. And zeolites decompose presulfiding agents at a lower temperature than nickel-molybdenum. The NiMo Ht method enriched the electrocatalyst with Mo atoms compared to the NiMo Elec approach, producing a similar current density with a minimal overpotential of 50 mV compared to Pt. Surface distortion as a unifying concept and descriptor in oxygen reduction reaction electrocatalysis. 53, pp. Hafner, J. Abinitio simulations of materials using VASP: densityfunctional theory and beyond. By submitting a comment you agree to abide by our Terms and Community Guidelines. New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism. Chen, Z. et al. Shinji Jomori, K. K., Nonoyama, N. & Manabu Kato, T. Y. The (33)-Ni(111), (33)-Mo(110), (33)-W(110), (33)-Pt(111), (11)-CoNi4(111), (11)-FeNi4(111), (11)-MoNi4(211), and (11)-WNi4(211) slabs with four layers and 15 vacuum layer were modeled to simulate the explored surfaces of metals and alloys. abstract = "A low-cost cathode catalyst based on a NiMo alloy was examined here to replace noble metals for the hydrogen production in microbial electrolysis cells (MECs). 8, 15437 (2017). In situ presulfided catalysts facilitate chemical reactions to convert feedstocks into final end-use products, but they do not become part of the finished products. ADS 7, 22552260 (2014). 131, 1075410759 (2019). Zhuang, Z. et al. The proposed electrocatalyst has been formulated. Soc. Ruggero Rossi, Joseph Nicolas, Bruce E. Logan, Research output: Contribution to journal Article peer-review. Sustainable Dev., 2011, no. 3, 697702 (2004). Mater. In its familiar powder form (elemental) sulfur is virtually impossible to use in the chemical reactions required in petroleum refining. Nickelcopper supported on a carbon black hydrogen oxidation catalyst integrated into an anion-exchange membrane fuel cell. 135, 1347313478 (2013). PubMed Chem. Its catalytic properties are different from the properties of conventional nickel catalysts. Google Scholar, Ghashghaee, M., Rev. Schmidt, T., Ross, P. Jr & Markovic, N. Temperature dependent surface electrochemistry on Pt single crystals in alkaline electrolytes: Part 2. Kresse, G. & Hafner, J. Ab initio molecular-dynamics simulation of the liquid-metalamorphous-semiconductor transition in germanium. Zaffran, J. Escudero-Escribano, M. et al. 148, pp. 52, 301303 (1960). 8189. 25052520. 2, pp. Adv. J. Phys. 110, 50295036 (1999). CAS Any other relevant data are also available from the corresponding authors upon reasonable request. Nat. https://doi.org/10.1007/s11244-013-0036-z, Hulea, V., Catal. Res., 2015, vol. For example, a low odor/low toxicity presulfiding agent that is biodegradable is desirable or one that allows easy clean-up of spills. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law. Meanwhile,. & Toroker, M. C. Understanding the oxygen evolution reaction on a two-dimensional NiO2 catalyst. 3, pp. Lett. 161, F458F463 (2014). Int. 31373148. Three chemical materials are necessary for presulfiding: (1) the sulfur-bearing agent; (2) the catalyst; and (3) hydrogen. Research output: Contribution to journal Article peer-review The remaining elements are scrubbed out and destroyed in an amine unit. Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions.
Improving plasma sprayed Raney-type nickel-molybdenum - Nature Enhanced electrocatalytic hydrogen oxidation on Ni/NiO/C derived from a Ni-based MOF. & Chukalina, M. Wavelet analysis of extended x-ray absorption fine structure data. Mitchell et al. 727, 887901 (2017). Compositional dependence of the fragility in metallic glass forming liquids. Spectrosc., 2007, vol. and EOH@cat. An RDE with glassy carbon (PINE with a diameter of 5.00mm and a disk area of 0.196cm2) was applied as the working electrode. 8, pp. The exchange correction treated for the transitional metals was based on the previous literatures, which includes the same metals as ours for reliability and comparability33,34,54. The adsorption energies of hydrogen and hydroxyl species with the explored catalysts were calculated according to EH-ads=EH@cat. Rev. . Commun. The presulfided catalyst causes a chemical reaction with the feedstock to produce the desired product. Radiat. By continuing you agree to the use of cookies. Mater. Cited October 13, 2021. Interfaces 4, 1601086 (2017). Nat. 1085, pp. Gaylord Chemical manufactures is an on-purpose producer of Dimethyl Sulfide (DMS). Inoue, A. doi = "10.1016/j.jpowsour.2022.232594", Using nickel-molybdenum cathode catalysts for efficient hydrogen gas production in microbial electrolysis cells, Institutes of Energy and the Environment (IEE), https://doi.org/10.1016/j.jpowsour.2022.232594, Renewable Energy, Sustainability and the Environment. & Nishiyama, N. New bulk metallic glasses for applications as magnetic-sensing, chemical, and structural materials. Am. WK9990000101, 30919011107 and 30919011404), the Natural Science Foundation of Jiangsu Province (grant no. A 5, 2443324443 (2017). The scientists incorporated nanograins of nickel-molybdenum catalyst onto the edges of magnesium oxide crystals. Electrocatalysis of the hydrogen oxidation reaction on carbon-supported bimetallic NiCu particles prepared by an improved wet chemical synthesis. Ed. ACS Catal. The carbon-supported nickel-molybdenum nitride (NiMoN x, see picture) catalyst had a nanoscale sheet structure comprising a few layers and an abundance of highly accessible reactive sites. Experimental proof of the bifunctional mechanism for the hydrogen oxidation in alkaline media. Modifying the closely stacked MEC design to include a reference electrode, and analysis of the electrode potentials using the electrode potential slope method, revealed a large contribution of the cathode resistance (5.3 0.5 m m2) compared to the anode (1.4 0.2 m m2) and ohmic resistance (0.83 m m2) for a total internal resistance of 7.6 0.5 m m2.
Molecules | Free Full-Text | Constructing Molybdenum Phosphide - MDPI Ind., 2014, vol. This catalyst also shows remarkable robustness in alkaline electrolyte with a wide stability window up to 0.8V versus the reversible hydrogen electrode. Using nickel-molybdenum cathode catalysts for efficient hydrogen gas production in microbial electrolysis cells. and C.G. Sci. 1, 781786 (2018). Rheinlnder, P. J., Herranz, J., Durst, J. The purpose of this publication is to present an overview of the presulfiding process. & Caspary Toroker, M. Benchmarking density functional theory based methods to model NiOOH material properties: Hubbard and van der Waals corrections vs hybrid functionals. A higher cost for this type of agent may be well justified by the economies achieved when complying with environmental and safety regulations. Catalyst: Sulfur Agent Nickel-molybdenum Cobalt-molybdenum, Dimethyl disulfide 68 228 F 61 F >575 F, Ethyl mercaptan 51.5 95 F <32 F >575 F, Di-tertiary nonylpolsulfide(TNPS) 37 320 F 250 F . This is a preview of subscription content, access via Proc. Berlich, A., Liu, Y. C. & Morgner, H. Evaporation of Ni and carbon containing species onto NiO/Ni as case study for metal support catalysts investigated by metastable induced electron spectroscopy (MIES). Here we report nickel-molybdenum-niobium metallic glasses as PGM-free HOR catalysts. Dekel, D. R. Review of cell performance in anion exchange membrane fuel cells. 2, pp. https://doi.org/10.1016/j.apcata.2003.10.010, Rajagopal, S., Marini, H.J., Marzari, J.A., and Miranda, R., J.
Catalytic Activity and Stability of Nickel Modified Molybdenum Carbide & Shao-Horn, Y. Hydrogen oxidation and evolution reaction kinetics on platinum: acid vs alkaline electrolytes. The CO-stripping current was obtained via cyclic voltammetry in a potential region from 0 to 1.2V at a sweep rate of 20mVs1. note = "Funding Information: This work was supported by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy (EERE ) under the award DE-EE0009623 . Radiat. 12, 38073812 (2016). CAS Nos, S. A unified formulation of the constant temperature molecular dynamics methods. BCC-phased PdCu alloy as a highly active electrocatalyst for hydrogen oxidation in alkaline electrolytes.
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